Favorite does work for individual cards in the collection.
Within the collection, not a specific card, just hover the mouse over any card.
Then see the heart symbol top right corner.
Click that and you have a favorite card.
Automatically this is added to the favorites playlist.
Simply click my playlists, then favorite. There you will see all cards marked as favorite, and this list can be added to the queue. Open the favorites and click on start to begin playing all favorited cards.